676551
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676551
Aldrich
Potassium 2-(3,5-di-tert-butyl-2-hydroxybenzylideneamino)-2,2-diphenylacetate
95%
| Synonym: | SALDIPAC, Potassium N-(3,5-di-tert-butylsalicylidene)-2-amino-2,2-diphenylacetate |
| Linear Formula: | C29H32KNO3 |
| Molecular Weight: | 481.67 |
| PubChem Substance ID: | 24884856 |
Description
| Application | SALDIPAC ligand used with Co(BF4)2 (cat. no. 399957) in a hydroazidation of unactivated olefins providing a simple synthesis of alkylazides.1 The azides, in turn, can be used in a copper-catalyzed cycloaddition with acetylenes providing 1,4-disubstitutedtriazoles.2 |
Properties
| assay | 95% |
| mp | 122.2-131.9 °C |
References
| Cited Reference | 1. J. Am. Chem. Soc. 127, 8294, (2005) Abstract |
| 2. Synthesis 2007, 3839 |
